మూస:థులియం మూలకము

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Thulium, 00Tm
Thulium
Pronunciation/ˈθjliəm/ (THEW-lee-əm)
Appearancesilvery gray
Standard atomic weight Ar°(Tm)
Thulium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Ununtrium Flerovium Ununpentium Livermorium Ununseptium Ununoctium


Tm

Md
erbiumthuliumytterbium
Groupమూస:Infobox element/symbol-to-group/format
Periodperiod 6
Block  f-block
Electron configuration[Xe] 4f13 6s2
Electrons per shell2, 8, 18, 31, 8, 2
Physical properties
Phase at STPsolid
Melting point1818 K ​(1545 °C, ​2813 °F)
Boiling point2003 K ​(1730 °C, ​3146 °F)
Density (near r.t.)9.32 g/cm3
when liquid (at m.p.)8.56 g/cm3
Heat of fusion16.84 kJ/mol
Heat of vaporization191 kJ/mol
Molar heat capacity27.03 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1117 1235 1381 1570 (1821) (2217)
Atomic properties
Oxidation states0,[3] +1,[4] +2, +3 (a basic oxide)
ElectronegativityPauling scale: 1.25
Ionization energies
  • 1st: 596.7 kJ/mol
  • 2nd: 1160 kJ/mol
  • 3rd: 2285 kJ/mol
Atomic radiusempirical: 176 pm
Covalent radius190±10 pm
Color lines in a spectral range
Spectral lines of thulium
Other properties
Natural occurrenceprimordial
Crystal structurehexagonal close-packed (hcp)
Hexagonal close packed crystal structure for thulium
Thermal expansionpoly: 13.3 µm/(m⋅K) (r.t.)
Thermal conductivity16.9 W/(m⋅K)
Electrical resistivitypoly: 676 nΩ⋅m (r.t.)
Magnetic orderingparamagnetic (at 300 K)
Young's modulus74.0 GPa
Shear modulus30.5 GPa
Bulk modulus44.5 GPa
Poisson ratio0.213
Vickers hardness520 MPa
Brinell hardness471 MPa
CAS Number7440-30-4
History
Namingafter Thule, a mythical region in Scandinavia
Discovery and first isolationPer Teodor Cleve (1879)
Isotopes of thulium
Template:infobox thulium isotopes does not exist
 Category: Thulium
| references

References

  1. "Standard Atomic Weights: Thulium". CIAAW. 2021.
  2. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; et al. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry (in ఇంగ్లీష్). doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. Yttrium and all lanthanides except Ce and Pm have been observed in the oxidation state 0 in bis(1,3,5-tri-t-butylbenzene) complexes, see Cloke, F. Geoffrey N. (1993). "Zero Oxidation State Compounds of Scandium, Yttrium, and the Lanthanides". Chem. Soc. Rev. 22: 17–24. doi:10.1039/CS9932200017. and Arnold, Polly L.; Petrukhina, Marina A.; Bochenkov, Vladimir E.; Shabatina, Tatyana I.; Zagorskii, Vyacheslav V.; Cloke (2003-12-15). "Arene complexation of Sm, Eu, Tm and Yb atoms: a variable temperature spectroscopic investigation". Journal of Organometallic Chemistry. 688 (1–2): 49–55. doi:10.1016/j.jorganchem.2003.08.028.
  4. La(I), Pr(I), Tb(I), Tm(I), and Yb(I) have been observed in MB8 clusters; see Li, Wan-Lu; Chen, Teng-Teng; Chen, Wei-Jia; Li, Jun; Wang, Lai-Sheng (2021). "Monovalent lanthanide(I) in borozene complexes". Nature Communications. 12 (1): 6467. doi:10.1038/s41467-021-26785-9. PMC 8578558. PMID 34753931.