మెగ్నీషియం

వికీపీడియా నుండి
ఇక్కడికి గెంతు: మార్గసూచీ, వెతుకు
మెగ్నీషియం
12Mg
హైడ్రోజన్ (diatomic nonmetal)
హీలియం (noble gas)
లిథియం (alkali metal)
బెరీలియం (alkaline earth metal)
బోరాన్ (metalloid)
కార్బన్ (polyatomic nonmetal)
నైట్రోజన్ (diatomic nonmetal)
ఆక్సిజన్ (diatomic nonmetal)
ఫ్లోరిన్ (diatomic nonmetal)
నియాన్ (noble gas)
సోడియం (alkali metal)
మెగ్నీషియం (alkaline earth metal)
అల్యూమినియం (poor metal)
సిలికాన్ (metalloid)
పాస్పరస్ (polyatomic nonmetal)
సల్ఫర్ (polyatomic nonmetal)
క్లోరిన్ (diatomic nonmetal)
ఆర్గాన్ (noble gas)
పొటాషియం (alkali metal)
కాల్షియం (alkaline earth metal)
Scandium (transition metal)
Titanium (transition metal)
Vanadium (transition metal)
Chromium (transition metal)
Manganese (transition metal)
Iron (transition metal)
Cobalt (transition metal)
Nickel (transition metal)
Copper (transition metal)
Zinc (transition metal)
Gallium (poor metal)
Germanium (metalloid)
Arsenic (metalloid)
Selenium (polyatomic nonmetal)
Bromine (diatomic nonmetal)
Krypton (noble gas)
Rubidium (alkali metal)
Strontium (alkaline earth metal)
Yttrium (transition metal)
Zirconium (transition metal)
Niobium (transition metal)
Molybdenum (transition metal)
Technetium (transition metal)
Ruthenium (transition metal)
Rhodium (transition metal)
Palladium (transition metal)
Silver (transition metal)
Cadmium (transition metal)
Indium (poor metal)
Tin (poor metal)
Antimony (metalloid)
Tellurium (metalloid)
Iodine (diatomic nonmetal)
Xenon (noble gas)
Caesium (alkali metal)
Barium (alkaline earth metal)
Lanthanum (lanthanoid)
Cerium (lanthanoid)
Praseodymium (lanthanoid)
Neodymium (lanthanoid)
Promethium (lanthanoid)
Samarium (lanthanoid)
Europium (lanthanoid)
Gadolinium (lanthanoid)
Terbium (lanthanoid)
Dysprosium (lanthanoid)
Holmium (lanthanoid)
Erbium (lanthanoid)
Thulium (lanthanoid)
Ytterbium (lanthanoid)
Lutetium (lanthanoid)
Hafnium (transition metal)
Tantalum (transition metal)
Tungsten (transition metal)
Rhenium (transition metal)
Osmium (transition metal)
Iridium (transition metal)
Platinum (transition metal)
Gold (transition metal)
Mercury (transition metal)
Thallium (poor metal)
Lead (poor metal)
Bismuth (poor metal)
Polonium (poor metal)
Astatine (metalloid)
Radon (noble gas)
Francium (alkali metal)
Radium (alkaline earth metal)
Actinium (actinoid)
Thorium (actinoid)
Protactinium (actinoid)
Uranium (actinoid)
Neptunium (actinoid)
Plutonium (actinoid)
Americium (actinoid)
Curium (actinoid)
Berkelium (actinoid)
Californium (actinoid)
Einsteinium (actinoid)
Fermium (actinoid)
Mendelevium (actinoid)
Nobelium (actinoid)
Lawrencium (actinoid)
Rutherfordium (transition metal)
Dubnium (transition metal)
Seaborgium (transition metal)
Bohrium (transition metal)
Hassium (transition metal)
Meitnerium (unknown chemical properties)
Darmstadtium (unknown chemical properties)
Roentgenium (unknown chemical properties)
Copernicium (transition metal)
Ununtrium (unknown chemical properties)
Flerovium (unknown chemical properties)
Ununpentium (unknown chemical properties)
Livermorium (unknown chemical properties)
Ununseptium (unknown chemical properties)
Ununoctium (unknown chemical properties)
Be

Mg

Ca
సోడియంమెగ్నీషియంఅల్యూమినియం
ఆవర్తన పట్టిక లో మెగ్నీషియం స్థానం
రూపం
shiny grey solid


Spectral lines of Magnesium
సాధారణ ధర్మములు
మూలకం పేరు, రసాయన సంకేతం, పరమాణు సంఖ్య మెగ్నీషియం, Mg, 12
ఉచ్ఛారణ /mæɡˈnziəm/
mag-NEE-zee-əm
మూలక వర్గం క్షారమృత్తిక లోహము
గ్రూపు, పీరియడ్, బ్లాకు 2 (alkaline earth metals), 3, s
ప్రామాణిక పరమాణు భారం 24.305(1)
ఎలక్ట్రాన్ విన్యాసం [Ne] 3s2
2, 8, 2
చరిత్ర
నామకరణం after Magnesia, Greece
ఆవిష్కరణ Joseph Black (1755)
మొదటి ఐసోలేషన్ Humphry Davy (1808)
భౌతిక ధర్మములు
పదార్థ స్థితి solid
సాంద్రత (near r.t.) 1.738 g·cm−3
ద్రవీభవన స్థానం వద్ద ద్రవరూప సాంద్రత 1.584 g·cm−3
ద్రవీభవన స్థానం 923 K, 650 °C, 1202 °F
మరుగు స్థానం 1363 K, 1091 °C, 1994 °F
సంలీనం యొక్క ఉష్ణం 8.48 kJ·mol−1
బాష్పీభవనోష్ణం 128 kJ·mol−1
మోలార్ హీట్ కెపాసిటీ 24.869 J·mol−1·K−1
బాష్ప పీడనం
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 701 773 861 971 1132 1361
పరమాణు ధర్మములు
ఆక్సీకరణ స్థితులు +2, +1[1]
(strongly basic oxide)
ఋణవిద్యుదాత్మకత 1.31 (Pauling scale)
అయనీకరణ శక్మములు
(మరిన్ని)
1st: 737.7 kJ·mol−1
2nd: 1450.7 kJ·mol−1
3rd: 7732.7 kJ·mol−1
పరమాణు వ్యాసార్థం 160 pm
సమయోజనీయ వ్యాసార్థం 141±7 pm
వాండర్ వాల్ వ్యాసార్థం 173 pm
వివిధ విషయాలు
స్ఫటిక నిర్మాణము hexagonal close-packed
మెగ్నీషియం has a hexagonal close packed crystal structure
అయస్కాంత పదార్థ రకం paramagnetic
విద్యున్నిరోధకత్వం మరియు వాహకత్వం (20 °C) 43.9 nΩ·m
ఉష్ణ వాహకత్వం 156 W·m−1·K−1
ఉష్ణ వ్యాకోచం (25 °C) 24.8 µm·m−1·K−1
ధ్వని వేగం (సన్నని కడ్డీ) (r.t.) (annealed)
4940 m·s−1
యంగ్ గుణకం 45 GPa
షీర్ మాడ్యూల్ 17 GPa
బల్క్ మాడ్యూల్స్ 45 GPa
పోయిస్సన్ నిష్పత్తి 0.290
Mohs ధృఢత 2.5
బ్రినెల్ దృఢత 260 MPa
సి.ఎ.యస్ రిజిస్ట్రీ సంఖ్య 7439-95-4
అతి స్థిరమైన ఐసోటోపులు
ప్రధానవ్యాసం: మెగ్నీషియం యొక్క ఐసోటోపులు
iso NA అర్థజీవితకాలం DM DE (MeV) DP
24Mg 78.99% Mg, 12 న్యూట్రాన్లతో స్థిరంగా ఉన్నది.
25Mg 10.00% Mg, 13 న్యూట్రాన్లతో స్థిరంగా ఉన్నది.
26Mg 11.01% Mg, 14 న్యూట్రాన్లతో స్థిరంగా ఉన్నది.
· సూచికలు


మెగ్నీషియం (ఉచ్చారణ: Mæɡni Ziəm) అనేది ఒక క్షారమృత్తిక లోహం. దీని సంకేతం Mg,దీని పరమాణు సంఖ్య 12 మరియు సాధారణ ఆక్సీకరణ సంఖ్య +2. ఇది భూమి ప్రావారములో ఎనిమిదవ విస్తారమైన మూలకం[2] మరియు విశ్వంలో గల అన్ని మూలకాలలో తొమ్మిదవది[3][4]. మెగ్నీషియం మొత్తం భూమిలో నాల్గవ సాధారణ మూలకం (దీనితోపాటు ఇనుము, ఆక్సిజన్, మరియు సిలికాన్ ఉంటాయి). ఒక గ్రహ ద్రవ్యరాశిలో 13% మరియు భూప్రావారం లో అధిక భాగంగా ఉన్నది.


The relative abundance of magnesium is related to the fact that it easily builds up in supernova stars from a sequential addition of three helium nuclei to carbon (which in turn is made from three helium nuclei). Due to magnesium ion's high solubility in water, it is the third most abundant element dissolved in seawater.[5]

The free element (metal) is not found naturally on Earth, as it is highly reactive (though once produced, it is coated in a thin layer of oxide (see passivation), which partly masks this reactivity). The free metal burns with a characteristic brilliant white light, making it a useful ingredient in flares. The metal is now mainly obtained by electrolysis of magnesium salts obtained from brine. Commercially, the chief use for the metal is as an alloying agent to make aluminium-magnesium alloys, sometimes called magnalium or magnelium. Since magnesium is less dense than aluminium, these alloys are prized for their relative lightness and strength.

In human biology, magnesium is the eleventh most abundant element by mass in the human body. Its ions are essential to all living cells, where they play a major role in manipulating important biological polyphosphate compounds like ATP, DNA, and RNA. Hundreds of enzymes thus require magnesium ions to function. Magnesium compounds are used medicinally as common laxatives, antacids (e.g., milk of magnesia), and in a number of situations where stabilization of abnormal nerve excitation and blood vessel spasm is required (e.g., to treat eclampsia). Magnesium ions are sour to the taste, and in low concentrations they help to impart a natural tartness to fresh mineral waters.

In vegetation, magnesium is the metallic ion at the center of chlorophyll, and is thus a common additive to fertilizers.[6]

మూలం మరియు లక్షణాలు[మార్చు]

భౌతిక మరియు రసాయన లక్షణాలు[మార్చు]

Elemental magnesium is a rather strong, silvery-white, light-weight metal (two thirds the density of aluminium). It tarnishes slightly when exposed to air, although unlike the alkali metals, an oxygen-free environment is unnecessary for storage because magnesium is protected by a thin layer of oxide that is fairly impermeable and difficult to remove. Like its lower periodic table group neighbor calcium, magnesium reacts with water at room temperature, though it reacts much more slowly than calcium. When submerged in water, hydrogen bubbles almost unnoticeably begin to form on the surface of the metal—though if powdered, it reacts much more rapidly. The reaction occurs faster with higher temperatures (see precautions). Magnesium's ability to react with water can be harnessed to produce energy and run a magnesium-based engine. Magnesium also reacts exothermically with most acids, such as hydrochloric acid (HCl). As with aluminium, zinc and many other metals, the reaction with hydrochloric acid produces the chloride of the metal and releases hydrogen gas.

Magnesium is a highly flammable metal, but while it is easy to ignite when powdered or shaved into thin strips, it is difficult to ignite in mass or bulk. Once ignited, it is difficult to extinguish, being able to burn in nitrogen (forming magnesium nitride), carbon dioxide (forming magnesium oxide and carbon) and water (forming magnesium oxide and hydrogen). This property was used in incendiary weapons used in the firebombing of cities in World War II, the only practical civil defense being to smother a burning flare under dry sand to exclude the atmosphere. On burning in air, magnesium produces a brilliant white light that includes strong ultraviolet. Thus magnesium powder (flash powder) was used as a source of illumination in the early days of photography. Later, magnesium ribbon was used in electrically ignited flash bulbs. Magnesium powder is used in the manufacture of fireworks and marine flares where a brilliant white light is required. Flame temperatures of magnesium and magnesium alloys can reach 3,100 °C (3,370 K; 5,610 °F),[7] although flame height above the burning metal is usually less than 300 mm (12 in).[8] Magnesium may be used as an ignition source for thermite, a mixture of aluminium and iron oxide powder that is otherwise difficult to ignite. Those properties are due to magnesium's high specific heat, the fourth highest specific heat among the metals.

Magnesium compounds are typically white crystals. Most are soluble in water, providing the sour-tasting magnesium ion Mg2+. Small amounts of dissolved magnesium ion contribute to the tartness and taste of natural waters. Magnesium ion in large amounts is an ionic laxative, and magnesium sulfate (common name: Epsom salt) is sometimes used for this purpose. So-called "milk of magnesia" is a water suspension of one of the few insoluble magnesium compounds, magnesium hydroxide. The undissolved particles give rise to its appearance and name. Milk of magnesia is a mild base commonly used as an antacid, which has some laxative side effect.

ఐసోటోపులు[మార్చు]

Magnesium has three stable isotopes: 24Mg, 25Mg and 26Mg. All are present in significant amounts (see table of isotopes above). About 79% of Mg is 24Mg. The isotope 28Mg is radioactive and in the 1950s to 1970s was made commercially by several nuclear power plants for use in scientific experiments. This isotope has a relatively short half-life (21 hours) and so its use was limited by shipping times.

26Mg has found application in isotopic geology, similar to that of aluminium. 26Mg is a radiogenic daughter product of 26Al, which has a half-life of 717,000 years. Large enrichments of stable 26Mg have been observed in the Ca-Al-rich inclusions of some carbonaceous chondrite meteorites. The anomalous abundance of 26Mg is attributed to the decay of its parent 26Al in the inclusions. Therefore, the meteorite must have formed in the solar nebula before the 26Al had decayed. Hence, these fragments are among the oldest objects in the solar system and have preserved information about its early history.

It is conventional to plot 26Mg/24Mg against an Al/Mg ratio. In an isochron dating plot, the Al/Mg ratio plotted is27Al/24Mg. The slope of the isochron has no age significance, but indicates the initial 26Al/27Al ratio in the sample at the time when the systems were separated from a common reservoir.

సృష్టి[మార్చు]

Magnesium is produced in stars larger than 3 solar masses by fusing helium and neon in the alpha process at temperatures above 600 megakelvins.

సంభవించినది[మార్చు]

Although magnesium is found in over 60 minerals, only dolomite, magnesite, brucite, carnallite, talc, and olivine are of commercial importance.

The Mg2+ cation is the second most abundant cation in seawater (occurring at about 12% of the mass of sodium there), which makes seawater and sea-salt an attractive commercial source of Mg. To extract the magnesium, calcium hydroxide is added to seawater to form magnesium hydroxide precipitate.

MgCl2 + Ca(OH)2 → Mg(OH)2 + CaCl2

Magnesium hydroxide (brucite) is insoluble in water so it can be filtered out, and reacted with hydrochloric acid to obtain concentrated magnesium chloride.

Mg(OH)2 + 2 HCl → MgCl2 + 2 H2O

From magnesium chloride, electrolysis produces magnesium.

ఉత్పత్తి[మార్చు]

Country 2011 production
(tonnes)[9]
China 661,000
U.S. (Capacity.
Production figures withheld
to avoid disclosing
company proprietary data.)
63,500
Russia 37,000
Israel 30,000
Kazakhstan 21,000
Brazil 16,000
Ukraine 2,000
Serbia 1,500

China is the dominant supplier of magnesium, with approximately 80% of the world market share. China is almost completely reliant on the silicothermic Pidgeon process (the reduction of the oxide at high temperatures with silicon) to obtain the metal.[10]

In the United States, magnesium is principally obtained by electrolysis of fused magnesium chloride from brines, wells, and sea water. At the cathode, the Mg2+ ion is reduced by two electrons to magnesium metal:

Mg2+ + 2 e|electron → Mg

At the anode, each pair of Cl|- ions is oxidized to chlorine gas, releasing two electrons to complete the circuit:

2 Cl- → Cl2 (g) + 2 e|electron

A new process, solid oxide membrane technology, involves the electrolytic reduction of MgO. At the cathode Mg2+ ion is reduced by two electrons to magnesium metal. The electrolyte is Yttria-stabilized zirconia(YSZ). The anode is a liquid metal. At the YSZ/liquid metal anode O2- is reduced. A layer of graphite borders the liquid metal anode, and at this interface carbon and oxygen react to form carbon monoxide. When silver is used as the liquid metal anode, there is no reductant carbon or hydrogen needed, and only oxygen gas is evolved at the anode.[11] It has been reported that this method provides a 40% reduction in cost per pound over the electrolytic reduction method.[12] This method is more environmentally sound than others because there is much less carbon dioxide emitted.

The United States has traditionally been the major world supplier of this metal, supplying 45% of world production even as recently as 1995. Today, the US market share is at 7%, with a single domestic producer left, US Magnesium, a Renco Group company in Utah born from now-defunct Magcorp.[13]

చరిత్ర[మార్చు]

The name magnesium originates from the Greek word for a district in Thessaly called Magnesia. It is related to magnetite and manganese, which also originated from this area, and required differentiation as separate substances. See manganese for this history.

Magnesium is the eighth most abundant element in the Earth's crust by mass and tied in seventh place with iron in terms of molarity.[2] It is found in large deposits of magnesite, dolomite, and other minerals, and in mineral waters, where magnesium ion is soluble. In 1618, a farmer at Epsom in England attempted to give his cows water from a well there. The cows refused to drink because of the water's bitter taste, but the farmer noticed that the water seemed to heal scratches and rashes. The substance became known as Epsom salts and its fame spread. It was eventually recognized as hydrated magnesium sulfate, MgSO4·7మూస:HspH2O.

The metal itself was first produced by Sir Humphry Davy in England in 1808. He used electrolysis on a mixture of magnesia and mercuric oxide.[14] Antoine Bussy prepared it in coherent form in 1831. Davy's first suggestion for a name was magnium,[14] but the name magnesium is now used.

అనువర్తనాలు[మార్చు]

లోహంగా[మార్చు]

An unusual application of magnesium as an illumination source while wakeskating in 1931

Magnesium is the third most commonly used structural metal, following iron and aluminium. It has been called the lightest useful metal by The Periodic Table of Videos.[15]

The main applications of magnesium are, in order: component of aluminium alloys, in die-casting (alloyed with zinc),[16] to remove sulfur in the production of iron and steel, the production of titanium in the Kroll process.[17]

Magnesium, in its purest form, can be compared with aluminium, and is strong and light, so it is used in several high volume part manufacturing applications, including automotive and truck components. Specialty, high-grade car wheels of magnesium alloy are called "mag wheels", although the term is often more broadly misapplied to include aluminium wheels.

The high magnesium content used for the crankcase of the late-World War II Wright Duplex Cyclone eighteen-cylinder radial aviation engine was a serious problem for the earliest examples of the Boeing B-29 heavy bomber, as engine fires in flight could ignite the engine crankcases, literally "torching" the wing spar apart in under a minute, causing wing failure.

An earlier Mercedes-Benz race car model, the Mercedes-Benz 300 SLR, had a body made from Elektron, a magnesium alloy; these cars ran (with successes) at Le Mans, the Mille Miglia, and other world-class race events in 1955 (though one was involved in the single worst accident in auto racing history, in terms of human casualties, at the Le Mans race.) Porsche's all-out quest to decrease the weight of their race cars led to the use of magnesium alloy frames in the famous 917/053 that won Le Mans in 1971, and still holds the absolute distance record.

Volkswagen Group has used magnesium in its engine components for many years. For a long time, Porsche used magnesium alloy for its engine blocks due to the weight advantage. There is renewed interest in magnesium alloy engine blocks, as featured in the 2006 BMW 325i and 330i models.

The BMW engine uses an aluminium alloy insert for the cylinder walls and cooling jackets surrounded by a high-temperature magnesium alloy AJ62A.

The application of magnesium AE44 alloy in the 2006 Corvette Z06 engine cradle has advanced the technology of designing robust automotive parts in magnesium. Both these alloys are recent developments in high-temperature low creep magnesium alloys.

Mitsubishi Motors also uses magnesium (branded magnesium alloy) for its paddle shifters. The general strategy for such alloys is to form intermetallic precipitates at the grain boundaries, for example by adding mischmetal or calcium.[18] New alloy development and lower costs that make magnesium competitive with aluminium will increase the number of automotive applications.[citation needed]

Products made of magnesium: firestarter and shavings, sharpener, magnesium ribbon

The second application field of magnesium is electronic devices. Because of low weight, good mechanical and electrical properties, magnesium is widely used for manufacturing of mobile phones, laptop and tablet computers, cameras, and other electronic components.

Historically, magnesium was one of the main aerospace construction metals and was used for German military aircraft as early as World War I and extensively for German aircraft in World War II.

The Germans coined the name 'Elektron' for magnesium alloy. The term is still used today. The application of magnesium in the commercial aerospace industry was generally restricted to engine related components, due either to perceived hazards with magnesium parts in the event of fire, or corrosion. Currently the use of magnesium alloys in aerospace is increasing, mostly driven by the increasing importance of fuel economy and the need to reduce weight.[citation needed] The development and testing of new magnesium alloys continues, notably Elektron 21, which has successfully undergone extensive aerospace testing for suitability in engine, internal and airframe components.[19] The European Community runs three R&D magnesium projects in the Aerospace priority of Six Framework Program.

సముచిత మెటల్ ఉపయోగాలు[మార్చు]

Magnesium, being readily available and relatively nontoxic, has a variety of uses:

  • Magnesium is flammable, burning at a temperature of approximately 3,100 °C (3,370 K; 5,610 °F),[7] and the autoignition temperature of magnesium ribbon is approximately 473 °C (746 K; 883 °F).[20] It produces intense, bright, white light when it burns. Magnesium's high combustion temperature makes it a useful tool for starting emergency fires. Other uses include flash photography, flares, pyrotechnics and fireworks sparklers. Magnesium is also often used to ignite thermite, or other materials that require a high ignition temperature.
    Magnesium firestarter (in left hand), used with a pocket knife and flint to create sparks that ignite the shavings
  • In the form of turnings or ribbons, to prepare Grignard reagents, which are useful in organic synthesis.
  • As an additive agent in conventional propellants and the production of nodular graphite in cast iron.
  • As a reducing agent for the production of uranium and other metals from their salts.
  • As a sacrificial (galvanic) anode to protect underground tanks, pipelines, buried structures, and water heaters.
  • Alloyed with zinc to produce the zinc sheet used in photoengraving plates in the printing industry, dry-cell battery walls, and roofing.[16]
  • As a metal, this element's principal use is as an alloying additive to aluminium with these aluminium-magnesium alloys being used mainly for beverage cans.

మెగ్నీషియం సమ్మేళనాలలో[మార్చు]

Magnesium compounds, primarily magnesium oxide (MgO), are used as a refractory material in furnace linings for producing iron, steel, nonferrous metals, glass and cement. Magnesium oxide and other magnesium compounds are also used in the agricultural, chemical, and construction industries.

Magnesium reacted with an alkyl halide gives a Grignard reagent, which is a very useful tool for preparing alcohols.

In agriculture and biology, the magnesium ion is necessary for all life (see magnesium in biology), so magnesium salts are frequently included in various foods, fertilizers (magnesium is a component of chlorophyll), and culture media.

సముచిత మరియు మెగ్నీషియం సమ్మేళనాలు సచిత్ర ఉపయోగాలు[మార్చు]

జీవసంబంధ[మార్చు]

Pharmaceutical preparations of magnesium are used to treat magnesium deficiency and hypomagnesemia, as well as eclampsia.[21] Usually in lower dosages, magnesium is commonly included in dietary mineral preparations, including many multivitamin preparations.

Sorted by type of magnesium salt, biological applications of magnesium include:

నిర్జీవ సంబంధమైన[మార్చు]
  • Dead-burned magnesite (magnesium oxide) is used for refractory purposes such as brick and liners in furnaces and converters.

Magnesium oxide from calcination is used as an electrical insulator in fire-resistant cables.[22]

జీవ పాత్ర[మార్చు]

Because of the important interaction between phosphate and magnesium ions, magnesium ions are essential to the basic nucleic acid chemistry of life, and thus are essential to all cells of all known living organisms. Over 300 enzymes require the presence of magnesium ions for their catalytic action, including all enzymes utilizing or synthesizing ATP, or those that use other nucleotides to synthesize DNA and RNA. ATP exists in cells normally as a chelate of ATP and a magnesium ion.

Plants have an additional use for magnesium in that chlorophylls are magnesium-centered porphyrins. Magnesium deficiency in plants causes late-season yellowing between leaf veins, especially in older leaves, and can be corrected by applying Epsom salts (which is rapidly leached), or else crushed dolomitic limestone to the soil.

refer to caption; follow link for complete description
Examples of food sources of magnesium

Magnesium is a vital component of a healthy human diet. Human magnesium deficiency (including conditions that show few overt symptoms) is relatively rare[23] although only 32% of people in the United States meet the RDA-DRI;[24] low levels of magnesium in the body has been associated with the development of a number of human illnesses such as asthma, diabetes, and osteoporosis.[25] Taken in the proper amount magnesium plays a role in preventing both stroke and heart attack. The symptoms of people with fibromyalgia, migraines, and girls going through their premenstrual syndrome are less severe and magnesium can shorten the length of the migraine symptoms.[26][27]

Adult human bodies contain about 24 grams of magnesium, with 60% in the skeleton, 39% intracellular (20% in skeletal muscle), and 1% extracellular.[28] Serum levels are typically 0.7–1.0 mmol/L or 1.8–2.4 mEq/L. Serum magnesium levels may appear normal even in cases of underlying intracellular deficiency, although no known mechanism maintains a homeostatic level in the blood other than renal excretion of high blood levels.

Intracellular magnesium is correlated with intracellular potassium. Magnesium is absorbed in the gastrointestinal tract, with more absorbed when status is lower. In humans, magnesium appears to facilitate calcium absorption[citation needed]. Low and high protein intake inhibit magnesium absorption, and other factors such as phosphate, phytate, and fat affect absorption. Absorbed dietary magnesium is largely excreted through the urine, although most magnesium "administered orally" is excreted through the feces.[29] Magnesium status may be assessed roughly through serum and erythrocyte Mg concentrations and urinary and fecal excretion, but intravenous magnesium loading tests are likely the most accurate and practical in most people.[30] In these tests, magnesium is injected intravenously; a retention of 20% or more indicates deficiency.[31] Other nutrient deficiencies are identified through biomarkers, but none are established for magnesium.[32]

Spices, nuts, cereals, coffee, cocoa, tea, and vegetables are rich sources of magnesium.[33] Green leafy vegetables such as spinach are also rich in magnesium as they contain chlorophyll. Observations of reduced dietary magnesium intake in modern Western countries compared to earlier generations may be related to food refining and modern fertilizers that contain no magnesium.[29]

Numerous pharmaceutical preparations of magnesium, as well as magnesium dietary supplements are available. Magnesium oxide, one of the most common forms in magnesium dietary supplements because it has high magnesium content per weight, has been reported the least bioavailable.[34][35] Magnesium citrate has been reported as more bioavailable than oxide or amino-acid chelate (glycinate) forms.[36]

Excess magnesium in the blood is freely filtered at the kidneys, and for this reason it is difficult to overdose on magnesium from dietary sources alone.[25] With supplements, overdose is possible, however, particularly in people with poor renal function; occasionally, with use of high cathartic doses of magnesium salts, severe hypermagnesemia has been reported to occur even without renal dysfunction.[37] Alcoholism can produce a magnesium deficiency, which is easily reversed by oral or parenteral administration, depending on the degree of deficiency.[38]

జీవ ద్రవాలలో డిటెక్షన్[మార్చు]

Magnesium concentrations in plasma or serum may be measured to monitor for efficacy and safety in those receiving the drug therapeutically, to confirm the diagnosis in potential poisoning victims or to assist in the forensic investigation in a case of fatal overdosage. The newborn children of mothers who received parenteral magnesium sulfate during labor may exhibit toxicity at serum magnesium levels that were considered appropriate for the mothers.[39]

చికిత్స నిరోధక మాంద్యం మెగ్నీషియం (TRD)[మార్చు]

There has been some speculation that magnesium deficiency can lead to depression. Cerebral spinal fluid (CSF) magnesium has been found low in treatment-resistant suicidal depression and in patients that have attempted suicide. Brain magnesium has been found low in TRD using phosphorus nuclear magnetic resonance spectroscopy, an accurate means for measuring brain magnesium. Blood and CSF magnesium do not appear well-correlated with major depression.[40] Magnesium chloride in relatively small doses was found as effective in the treatment of depressed elderly type 2 diabetics with hypomagnesemia as imipramine 50 mg daily.[41]

వ్యాథులలో మెగ్నీషియం[మార్చు]

Results from a meta-analysis of randomized clinical trials demonstrated that magnesium supplementation lowers high blood pressure in a dose dependent manner.[42] Low serum magnesium levels are associated with metabolic syndrome, diabetes mellitus type 2 and hypertension.[43] Low serum magnesium levels have been associated with a higher risk of developing metabolic syndrome.[44] Magnesium therapy is recommended by the ACC/AHA/ESC 2006 Guidelines for Management of Patients With Ventricular Arrhythmias and the Prevention of Sudden Cardiac Death for patients with ventricular arrhythmia associated with torsade de pointes who present with long QT syndrome as well as for the treatment of patients with digoxin intoxication-induced arrhythmias.[45] Magnesium is also the drug of choice in the management of pre-eclampsia and eclampsia.[46]

Besides its therapeutic role, magnesium has an additional beneficial effect on calcification. Patients with chronic kidney disease have a high prevalence of vascular calcification, and cardiovascular disease is the leading cause of death in this population. Several in vitro and animal studies point towards a protective role of magnesium through multiple molecular mechanisms. Magnesium is a natural calcium antagonist and both human and animal studies have shown that low circulating magnesium levels are associated with vascular calcification.[47] Results from an observational study conducted in the general Japanese population demonstrated that lower serum magnesium levels were significantly and independently associated with a greater average intima-media thickness and the risk of at least two carotid plaques.[48] Magnesium supplementation might be useful in reducing the progression of atherosclerosis in chronic dialysis patients.[49] Low serum magnesium may be an independent risk factor for death in patients with chronic kidney disease,[50] and patients with mildly elevated serum magnesium levels could have a survival advantage over those with lower magnesium levels.[51]

మెగ్నీషియం మెటల్ కోసం జాగ్రత్తలు[మార్చు]

Magnesium metal and its alloys are explosive hazards; they are highly flammable in their pure form when molten or in powder or ribbon form. Burning or molten magnesium metal reacts violently with water. When working with powdered magnesium, safety glasses with welding eye protection are employed, because the bright white light produced by burning magnesium contains ultraviolet light that can permanently damage the retinas of the eyes.[52]

Magnesium is capable of reducing water to highly flammable hydrogen gas:[53]

Mg (s) + 2 H2O (l) → Mg(OH)2 (s) + H2 (g)

As a result, water cannot extinguish magnesium fires. The hydrogen gas produced only intensifies the fire. Dry sand is an effective smothering agent, but only on relatively level and flat surfaces.

Magnesium also reacts with carbon dioxide to form magnesium oxide and carbon:

2 Mg (s) + CO2 → 2 MgO (s) + C (s)

hence, carbon dioxide fire extinguishers cannot be used for extinguishing magnesium fires either.[54]

Burning magnesium is usually quenched by using a Class D dry chemical fire extinguisher, or by covering the fire with sand or magnesium foundry flux to remove its air source.

యివి కూడా చూడండి[మార్చు]

సూచికలు[మార్చు]

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యితర లింకులు[మార్చు]